Resonant X-ray emission spectroscopy reveals d-d ligand-field states involved in the self-assembly of a square-planar platinum complex.
نویسندگان
چکیده
Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2':6',2''-terpyridine), and determine the effect of weak metal-metal and π-π interactions on their energy.
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ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 14 44 شماره
صفحات -
تاریخ انتشار 2012